FBR-Fenton Chemical Treatment Technology

Introduction

Chemical oxidation is to decompose organics to carbon dioxide and water with oxidant, and the most effective technology is Advanced Oxidation Processes (AOPs). Fenton technology is one of AOPs, which utilizes H2O2 to generate ‧OH (the oxidation potential is only lower than fluorine) using Fe2+ as catalyst. The mechanism is:

H2O2 + Fe2+ → ‧OH + OH- + Fe3+ → Fe(OH)3

FBR-Fenton oxidation (FentonⅣ) is one kind of Fenton family methods. The idea of FBR-Fenton oxidation combines homogeneous Fenton oxidation, heterogeneous H2O2/FeOOH oxidation, fluidized-bed crystallization and reduction/dissolution of FeOOH. The suitable range of COD is less than 500 mg/L. The advantages of FBC-Fenton oxidation are low dosage of Fe2+ and decrease 60% generated sludge compared to Fenton oxidation.

The advantages of Fenton regent are:

  1. Environmentally friendly：Not like other oxidants such as NaOCl, no chlorinated organic byproducts generates.
  2. Small construction space：The oxidation is fast so that the required reaction time is only 0.5~2 hrs compared to bio-treatment. Therefore, the space of reactor can be reduced.
  3. High flexibility：During operation, when high concentration wastewater occurs, it only needs to increase the dosages of Fe2+ and H2O2.
  4. Easy to operate：Only chemical addition and pH control are required.
  5. Low installation cost：Only 1/3~1/4 compared to conventional bio-treatment system.
  6. Strong oxidation：Many kinds of toxic chemicals such as vinyl chloride, BTEX, chlorobenzene, 1,4Dioxane, aldehyde, pentachlorophenol, polychlorinated biphenyl, TCE, DCE, PCE, EDTA, MTBE, MEK, etc.

Application

Color, foam and COD removal of Chemical, Textile, Pulp&Paper and Dyeing Industry. The COD of treated water can be less than 100 mg/L.

Application

  • NINGBO BEILUN QIANHE ENVIRONMENTAL ENGINNERING CORP. (Process Wastewater；720CMD)
  • SICHUAN HUAQIAO FENGHUANG PAPER INDUSTRY CO., LTD. (Process Wastewater；10,000CMD)
  • CHENG LOONG CORP. (Process Wastewater；20,000CMD)
  • BAOSTEEL ZHANGJIANG IRON & STEEL CORP. (Process Wastewater；3,600CMD)
  • YUEN FOONG YU PAPER MFG. CO., LTD. (Process Wastewater；16,000CMD)
  • YUEN FOONG YU PAPER MFG. CO., LTD. (Process Wastewater；18,000CMD)
  • McWONG ENVIRONMENTAL & ENERGY GROUP (Process Wastewater；1,200CMD)
  • ASIA SYMBOL (SHANDONG) PULP AND PAPER CO., LTD (Process Wastewater；160,000CMD)
  • UNIVERSAL PULP AND PAPER (SHANDONG) CO. LTD (Process Wastewater；25,000CMD)
  • DING FENG PAPER CO.,LTD. (GUANGDONG CHINA) (Process Wastewater；12,500CMD)
  • HUATAI PAPER CO., LTD. (ANHUI CHINA) (Process Wastewater；30,000CMD)
  • WUXI LONG CHEN PAPER CO., LTD. (JIANGSU CHINA) (Process Wastewater；20,000CMD)
  • GUANGDONG YIN ZHOU HU PAPER BASE (GUANGDONG CHINA) (Process Wastewater；20,000CMD)
  • HUATAI PAPER CO., LTD. (SHANDONG CHINA) (Process Wastewater；64,000CMD)
  • NINGBO ASIA PULP＆PAPER CO.,LTD. (ZHEJIANG CHINA) (Process Wastewater；40,000CMD)
  • ANGEL YEAST CO., LTD., (SHINJANG CHINA) (Process Wastewater；8,300CMD)
  • RUISHENG ELECTRONIC TECHNOLOGY (DONGGUAN CHINA) (Process Wastewater；3,000CMD)
  • HAINAN JINHAI PULP & PAPER CO., LTD. (HAINAN CHINA) (Process Wastewater；86,000CMD)
  • LEE & MAN PAPER MANUFACTURING LTD. (CHONGCING CHINA) (30,000CMD)
  • ARES GREEN TECHNOLOGY CORP. (Process Wastewater；13CMD)
  • BAOTAI SHOE FACTORY (DONGGUAN CHINA) (Process Wastewater；6,400CMD)
  • BEI LI CO., LTD. (Process Wastewater；1,200CMD)
  • PUCHENG CLEAN ENERGY CHEMICAL CO. LTD. (Process Wastewater；14,400CMD)
  • ZHENJIANG GPPC CHEMICAL CO., LTD. (Process Wastewater；)
  • ETERNAL MATERIALS CO.,LTD. (Process Wastewater；200CMD)
  • CHANG CHUN CHEMICAL (PANJIN) CO.,LTD. (Process Wastewater；6,880CMD)
  • FORMOSA LABORATORIES INC. (Process Wastewater；1,000CMD)
  • NANTEX INDUSTRY CO., LTD (Process Wastewater；1,600CMD)
  • CHANG CHUN PETROCHEMICAL CO., LTD. (Process Wastewater；4,000CMD)
  • FORMOSA ABS PLASTICS (NINGBO) CO.,LTD. (Process Wastewater；4,000CMD)
  • DEPARTMENT OF CHEMICAL ENGINEERING. NCKU (Process Wastewater；)
  • ENVIRONMENTAL PROTECTION ADMINISTRATION, R.O.C. (Process Wastewater；50CMD)
  • FORMOSA CHEMICALS & FIBRE CORP. (Process Wastewater；4,000CMD)
  • GUANGDONG SHAONENG GROUP CO., LTD. ZHUJI PAPER INDUSTRY BRANCH (Process Wastewater；5,700CMD)
  • DING FENG PAPER CO.,LTD. (GUANGDONG CHINA) (Process Wastewater；12,500CMD)
  • PUCHENG CLEAN ENERGY CHEMICAL CO. LTD. (Process Wastewater；6,744CMD)
  • CHANG CHUN CHEMICAL (PANJIN) CO.,LTD. (Process Wastewater；2,200CMD)
  • CHANGCHUN PLASTICS. CO. LTD. (Process Wastewater；6,880CMD)
  • NANTEX INDUSTRY CO., LTD (Process Wastewater；1,600CMD)
  • CHANG CHUN (JIANGSU) PETROCHEMICAL CO., LTD. (Process Wastewater；)
  • CHANG CHUN CHEMICAL (ZHANGZHOU) CO., LTD. (Process Wastewater；1,000CMD)
  • RIZHAO HUATAI PAPER CO., LTD. (Process Wastewater；25,000CMD)
  • CHANG CHUN CHEMICAL (ZHANGZHOU) CO., LTD. (Chemical Wastewater；1,000CMD)
  • DATONG YUDONG NEW DISTRICT WASTEWATER TREATMENT PLANT (Effluent of Biological treatment；10,000CMD)
  • SHANDONG SUN HONGHE PAPER CO., LTD. (Process Wastewater；20,000CMD)
  • FAR EASTERN POLYTEX (VIETNAM) LTD. (Effluent of Biological treatment；4,500CMD)
  • XIN SHI WASTEWATER TREATMENT PLANT (Effluent of MSBR biochemical treatment；20,000CMD)
  • FUJIAN TAIQING LEATHER CO., LTD. (Process wastewater；2,000CMD)
  • FAR EASTERN POLYTEX (VIETNAM) LTD. (Process Wastewater；7,500CMD)
  • ZIBO ZHUTAI RUNKUN BIOLOGICAL TECHNOLOGY CO., LTD. (Effluent of Pretreatment and Biochemical Treatment；10,000CMD)
  • DATONG YUDONG NEW DISTRICT WASTEWATER TREATMENT PLANT (Effluent of Pretreatment and Biochemical Treatment；60,000CMD)
  • VATVA CETP (Effluent of biological treatment；30,000CMD)
  • RANHILL (YONGXIN) WATER TREATMENT CO., LTD. (Industrial Wastewater；1,500CMD)
  • Croslene Chemical Industries Ltd. (Wastewater after biotreatment；368CMD)